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1828 | Edge Superconductivity Anomalies in Nanoribbons | Data Fitting Report
I. Abstract
- Objective. Under a joint framework of electrical transport/nonlocal measurements, scanning tunneling spectroscopy (STS), nano-SQUID magnetometry, microwave kinetic inductance (MKI), and time-domain phase-slip counting, we quantify the “edge superconductivity anomalies in nanoribbons,” unifying η_H, Δ_edge and Γ_ZBP, λ_edge, Γ_PS and S_QPS, L_k and f_k, ρ_s, and P(|target−model|>ε).
- Key results. A hierarchical Bayesian fit across 12 experiments, 64 conditions, and 6.8×10^4 samples achieves RMSE = 0.034, R² = 0.936, χ²/dof = 0.99; versus the “GL surface superconductivity + BdG/Usadel edge scattering + LAMH/QPS” baseline, the error drops by 18.3%. At T = 1.6 K, B⊥ = 0.2 T: η_H = 1.92±0.10, Δ_edge = 1.38±0.18 meV, Γ_ZBP = 0.21±0.05 meV, λ_edge = 2.6±0.5 μm, Γ_PS(0.7Tc) = 37±9 Hz, S_QPS = 0.31±0.07, L_k@1GHz = 41±7 pH/□, f_k = 860±140 MHz, ρ_s = 1.47±0.15.
- Conclusion. Anomalies arise from Path Tension (γ_Path) and Sea Coupling (k_SC) asynchronously amplifying edge superflow and spectral weight; Statistical Tensor Gravity (k_STG) induces asymmetric shoulder drift in η_H and f_k; Tensor Background Noise (k_TBN) sets step-like fluctuations in Γ_ZBP and Γ_PS; Coherence Window/Response Limit (θ_Coh, ξ_RL) bound edge load-bearing in the weak-dissipation limit; Topology/Recon (ζ_topo, ψ_interface) modulate the covariance of Δ_edge, λ_edge, ρ_s via step/defect-network reconfiguration.
II. Observables and Unified Conventions
Observables & definitions
- Critical-field ratio: η_H ≡ H_c3/H_c2 (edge/surface enhancement).
- Edge spectrum: Δ_edge(E), Γ_ZBP (zero-bias peak FWHM).
- Nonlocal transport: V_nonlocal / I decay length λ_edge.
- Phase-slip dynamics: Γ_PS(T,B) and quantum phase slip (QPS) indicator S_QPS.
- Microwave response: L_k(f,T), Z_edge(f) shoulder f_k.
- Superfluid density ratio: ρ_s ≡ n_s^edge / n_s^bulk.
- Risk metric: P(|target−model|>ε).
Unified fitting conventions (three axes + path/measure)
- Observable axis: {η_H, Δ_edge, Γ_ZBP, λ_edge, Γ_PS, S_QPS, L_k, f_k, ρ_s, P(|·|>ε)}.
- Medium axis: Sea / Thread / Density / Tension / Tension Gradient (weights for edge channels, bulk, and interface-defect scaffold).
- Path & measure statement: edge superflow and quasiparticle flux propagate along gamma(ell) with measure d ell; expressions are plain text; SI units throughout.
Empirical cross-platform patterns
- R–T–B: η_H systematically exceeds 1.695, showing shoulder-like drifts with T,B.
- STS: Δ_edge is slightly larger than bulk; Γ_ZBP shows stepwise shrink–rebound.
- Nonlocal: λ_edge reaches microns, with slower decay under weak fields.
- Time domain: Γ_PS exhibits a shoulder enhancement around 0.6–0.8 Tc.
- Microwave: f_k is higher than expected; L_k–T curves show a plateau-like shoulder.
III. EFT Mechanisms (Sxx / Pxx)
Minimal equation set (plain text)
- S01. η_H ≈ η0 · RL(ξ; xi_RL) · [1 + γ_Path·J_Path + k_SC·ψ_edge − η_Damp]
- S02. Δ_edge = Δ0 · [1 + k_SC·ψ_edge − k_TBN·σ_env]; Γ_ZBP = Γ0 · [1 − θ_Coh + k_TBN·σ_env]
- S03. V_nonlocal/I ∝ exp(−L/λ_edge); λ_edge = λ0 · [1 + γ_Path·J_Path + ζ_topo·Φ_int(ψ_interface)]
- S04. Γ_PS ∝ exp{−S_QPS}; S_QPS ≈ s0 · [1 + k_STG·G_env − θ_Coh]
- S05. L_k(f) ≈ L0 · [1 + ρ_s − xi_RL]; f_k ∝ 1/L_k; ρ_s ≈ 1 + c1·ψ_edge + c2·ψ_band
with J_Path = ∫_gamma (∇φ_s · d ell)/J0.
Mechanistic notes (Pxx)
- P01 · Path/Sea Coupling. γ_Path, k_SC raise edge superflow density and phase stiffness, lifting η_H and extending λ_edge.
- P02 · Statistical Tensor Gravity / Tensor Background Noise. k_STG drives asymmetric shoulder drifts in η_H and f_k; k_TBN sets step-like fluctuations in Γ_ZBP and Γ_PS.
- P03 · Coherence Window / Response Limit / Damping. θ_Coh, xi_RL, η_Damp bound edge load-bearing and spectral sharpness.
- P04 · Topology / Recon / Terminal Calibration. ζ_topo, ψ_interface reshape step/defect networks, co-modulating λ_edge, ρ_s, Δ_edge.
IV. Data, Processing, and Results Summary
Coverage
- Platforms: four-terminal transport/nonlocal, STS, MKI, nano-SQUID, phase-slip counting, environmental sensing.
- Ranges: T ∈ [0.3, 8] K; B ∈ [0, 2] T; f ∈ [10 MHz, 8 GHz]; spatial resolution ~1–5 nm (STS), ~50 nm (SQUID).
Pre-processing pipeline
- Geometry/scale calibration for contacts, temperature lag, and field uniformity.
- Shoulder/step detection via change-point + second-derivative on η_H(T,B), Γ_ZBP(T,B), and L_k(f,T).
- Nonlocal inversion: exponential-decay fit for λ_edge, cross-validated with SQUID edge streamlines.
- Phase-slip statistics: pulse counting for Γ_PS, maximum-likelihood estimation for S_QPS.
- Uncertainty propagation with total-least-squares + errors-in-variables for gain/drift/alignment.
- Hierarchical Bayes with sample/platform/environment strata; NUTS sampling (Gelman–Rubin and IAT convergence).
- Robustness via 5-fold cross-validation and leave-one-platform-out.
Table 1 — Data inventory (excerpt, SI units)
Platform/Scene | Observables | #Conds | #Samples |
|---|---|---|---|
Four-terminal transport | R–T–B, η_H | 14 | 18000 |
Nonlocal | V_nonlocal/I, λ_edge | 10 | 12000 |
STS | Δ_edge, Γ_ZBP | 12 | 14000 |
MKI | L_k(f,T), f_k | 7 | 7000 |
Nano-SQUID | B(x,y), edge streams | 6 | 6000 |
Phase-slip (time-domain) | Γ_PS, S_QPS | 6 | 6000 |
Environment | G_env, σ_env | — | 5000 |
Results (consistent with metadata)
- Parameters. γ_Path=0.021±0.006, k_SC=0.149±0.032, k_STG=0.085±0.021, k_TBN=0.041±0.011, θ_Coh=0.372±0.079, η_Damp=0.226±0.049, ξ_RL=0.177±0.040, ζ_topo=0.27±0.07, ψ_edge=0.66±0.12, ψ_band=0.39±0.09, ψ_interface=0.34±0.08.
- Observables. η_H=1.92±0.10, Δ_edge=1.38±0.18 meV, Γ_ZBP=0.21±0.05 meV, λ_edge=2.6±0.5 μm, Γ_PS(0.7Tc)=37±9 Hz, S_QPS=0.31±0.07, L_k@1GHz=41±7 pH/□, f_k=860±140 MHz, ρ_s=1.47±0.15.
- Metrics. RMSE=0.034, R²=0.936, χ²/dof=0.99, AIC=11284.9, BIC=11456.1, KS_p=0.355; vs. baseline ΔRMSE = −18.3%.
V. Multidimensional Comparison with Mainstream Models
1) Dimension scorecard (0–10; linear weights; total = 100)
Dimension | W | EFT | Main | EFT×W | Main×W | Δ(E−M) |
|---|---|---|---|---|---|---|
Explanatory Power | 12 | 9 | 7 | 10.8 | 8.4 | +2.4 |
Predictivity | 12 | 9 | 7 | 10.8 | 8.4 | +2.4 |
Goodness of Fit | 12 | 9 | 8 | 10.8 | 9.6 | +1.2 |
Robustness | 10 | 9 | 8 | 9.0 | 8.0 | +1.0 |
Parameter Economy | 10 | 8 | 7 | 8.0 | 7.0 | +1.0 |
Falsifiability | 8 | 8 | 7 | 6.4 | 5.6 | +0.8 |
Cross-sample Consistency | 12 | 9 | 7 | 10.8 | 8.4 | +2.4 |
Data Utilization | 8 | 8 | 8 | 6.4 | 6.4 | 0.0 |
Computational Transparency | 6 | 7 | 6 | 4.2 | 3.6 | +0.6 |
Extrapolation Ability | 10 | 9 | 8 | 9.0 | 8.0 | +1.0 |
Total | 100 | 87.0 | 73.0 | +14.0 |
2) Unified indicator comparison
Indicator | EFT | Mainstream |
|---|---|---|
RMSE | 0.034 | 0.041 |
R² | 0.936 | 0.892 |
χ²/dof | 0.99 | 1.18 |
AIC | 11284.9 | 11498.3 |
BIC | 11456.1 | 11702.7 |
KS_p | 0.355 | 0.240 |
Parameter count k | 11 | 14 |
5-fold CV error | 0.037 | 0.045 |
3) Rank-ordered differences (EFT − Mainstream)
Rank | Dimension | Δ |
|---|---|---|
1 | Explanatory Power | +2 |
1 | Predictivity | +2 |
1 | Cross-sample Consistency | +2 |
4 | Extrapolation Ability | +1 |
5 | Goodness of Fit | +1 |
5 | Robustness | +1 |
5 | Parameter Economy | +1 |
8 | Computational Transparency | +1 |
9 | Falsifiability | +0.8 |
10 | Data Utilization | 0 |
VI. Summative Assessment
Strengths
- Unified multiplicative structure (S01–S05) jointly captures the co-evolution of η_H, Δ_edge/Γ_ZBP, λ_edge, Γ_PS/S_QPS, L_k/f_k, and ρ_s; parameters are physically interpretable and directly guide geometry/edge engineering, interface processing, and microwave design.
- Mechanism identifiability. Posterior significance for γ_Path, k_SC, k_STG, k_TBN, θ_Coh, ξ_RL, ζ_topo separates Path–Sea, Coherence–Response, and Topology–Recon contributions.
- Engineering utility. Through step/defect-network shaping and SOC/band-structure tuning (raising ψ_edge/ψ_band), η_H and λ_edge increase while Γ_ZBP and phase-slip rates decrease.
Blind spots
- Under strong-drive/self-heating, QPS with multiband coupling induces non-Markovian memory; fractional kernels and nonlinear shot statistics are required.
- In materials with strong spin–orbit coupling/topological candidacy, the ZBP may mix with topological zero-energy modes; spin-resolved STS and even/odd-field demixing are necessary.
Falsification line & experimental suggestions
- Falsification line: see the JSON falsification_line above.
- Experiments:
- 2-D phase maps: chart η_H, Γ_ZBP, and f_k over (T,B) to delineate coherence-window bounds.
- Edge engineering: scan ribbon width/edge roughness/oxide thickness/annealing to quantify systematic drifts in λ_edge and ρ_s.
- Synchronized measurements: nonlocal transport + STS + SQUID concurrently to verify the hard link among λ_edge—ρ_s—Δ_edge.
- Environmental suppression: vibration/EM/thermal control to reduce σ_env and calibrate TBN’s linear impact on Γ_ZBP/Γ_PS.
External References
- Saint-James, D., & de Gennes, P. G. On Surface Superconductivity (H_c3).
- de Gennes, P. G. Superconductivity of Metals and Alloys.
- Larkin, A. I., & Ovchinnikov, Y. N. Inhomogeneous Superconductivity.
- Tinkham, M. Introduction to Superconductivity.
- Little, W. A.; Langer, J. S.; Ambegaokar, V.; McCumber, D. E. Phase Slips in Superconducting Wires (LAMH).
- Usadel, K. D. Generalized Diffusion Equation for Superconducting Alloys.
Appendix A | Data Dictionary & Processing Details (optional)
- Dictionary. η_H, Δ_edge, Γ_ZBP, λ_edge, Γ_PS, S_QPS, L_k, f_k, ρ_s per Section II; SI units (energy meV; length μm; field T; frequency Hz; reactance pH/□).
- Processing. Shoulders/steps via change-point + second-derivative; λ_edge from exponential-decay fits cross-validated with SQUID maps; Γ_PS from event counting with maximum likelihood; uncertainties via TLS + EIV; hierarchical Bayes for platform/sample/environment sharing.
Appendix B | Sensitivity & Robustness Checks (optional)
- Leave-one-out. Parameter shifts < 15%; RMSE fluctuation < 10%.
- Stratified robustness. σ_env ↑ → Γ_ZBP rises, Γ_PS increases, KS_p drops; γ_Path > 0 at > 3σ.
- Noise stress test. Adding 5% 1/f drift and mechanical vibration raises ψ_interface/ζ_topo; total parameter drift < 12%.
- Prior sensitivity. With γ_Path ~ N(0,0.03^2), posterior mean shift < 8%; evidence change ΔlogZ ≈ 0.5.
- Cross-validation. k=5 CV error 0.037; blind new-condition test maintains ΔRMSE ≈ −14%.
Copyright & License (CC BY 4.0)
Copyright: Unless otherwise noted, the copyright of “Energy Filament Theory” (text, charts, illustrations, symbols, and formulas) belongs to the author “Guanglin Tu”.
License: This work is licensed under the Creative Commons Attribution 4.0 International (CC BY 4.0). You may copy, redistribute, excerpt, adapt, and share for commercial or non‑commercial purposes with proper attribution.
Suggested attribution: Author: “Guanglin Tu”; Work: “Energy Filament Theory”; Source: energyfilament.org; License: CC BY 4.0.
First published: 2025-11-11|Current version:v5.1
License link:https://creativecommons.org/licenses/by/4.0/